Aluminum

13

Al

26.9815386

  • Name: Aluminum
  • Symbol: Al
  • Atomic number: 13
  • Atomic weight: 26.9815386
  • CAS Registry ID: 7429-90-5
  • Group name: (none)
  • Period number: 3
  • Block: p-block
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Description

Aluminum is one of the poor metals that is a silver colored solid in its natural state. Aluminum has an atomic weight of 26.9815386, a melting point of 1220.58 °F, and a boiling point of 4566 °F. Aluminum is the most abundant metal in the Earth’s crust, and it is used for a variety of purposes. Some of the more common uses of aluminum include: as a powder in the composition of paints, pyrotechnics, and thermites, as a solid for construction of transportation vehicles, and in the manufacture of cooking utensils.

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Isolation

Aluminum is a highly reactive metal and so it is not found free in nature. While different isolation processes are possible, only a few are used due to energy costs.

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The largest source for aluminum that is used for large scale commercial isolation is from bauxite. Bauxite is a type of ore that is striped mined because of its large aluminum content. The process which is used to isolate aluminum from bauxite is called the Bayer process. During this process, the bauxite ore is combined with sodium hydroxide and heated under pressure to approximately 392 °F. The result is a solution which contains sodium aluminate and sodium silicate. In the next step of the Bayer process, carbon dioxide is run through the solution resulting in a precipitate of aluminum hydroxide. The aluminum hydroxide is then filtered, washed, and heated to form alumina, (Al2O3). The final step used to separate pure aluminum from alumina is performed by using electrolysis. To minimize the energy that is needed for the electrolysis step, carbon lined steel cells are used as the cathodes and anodes for this reaction.


General
Name Aluminium
Symbol Al
Number 13
Chemical series poor metals
Group 13
Period 3
Block p
Appearance silvery
Standard atomic weight 26.9815386123499036(8)?g·mol-1
Electron configuration [Ne] 3s2 3p1
Electrons per shell 2, 8, 3
Atomic properties
Crystal structure face centered cubic 0.4032 nm
Oxidation states 3 (amphoteric oxide)
Electronegativity 1.61 (Pauling scale)
Ionization energies 1st: 577.5 kJ·mol-1
(more) 2nd: 1816.7 kJ·mol-1
(more) 3rd: 2744.8 kJ·mol-1
Atomic radius 125 pm
Atomic radius (calc.) 118 pm
Covalent radius 118 pm
Van der Waals radius
Physical properties
Phase solid
Density (near r.t.) 2.70 g·cm-3
Liquid density at m.p. 2.375 g·cm-3
Melting point 933.47 K (660.32 °C, 1220.58 °F)
Boiling point 2792 K (2519 °C, 4566 °F)
Critical point
Heat of fusion 10.71 kJ·mol-1
Heat of vaporization 294.0 kJ·mol-1
Heat capacity (25 °C) 24.200 J·mol-1·K-1
Miscellaneous
Magnetic ordering paramagnetic
Electrical resistivity (20 °C) 26.50 nΩ·m
Thermal conductivity (300 K) 237 W·m−1·K−1
Thermal expansion (25 °C) 23.1 µm·m−1·K−1
Speed of sound (thin rod) (r.t.) (rolled) 5000 m·s−1
Young's modulus 70 GPa
Shear modulus 26 GPa
Bulk modulus 76 GPa
Poisson ratio 0.35
Mohs hardness 2.75
Vickers hardness 167 MPa
Brinell hardness 245 MPa
CAS registry number 7429-90-5

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