Bismuth

83

Bi

208.98040(

  • Name: Bismuth
  • Symbol: Bi
  • Atomic number: 83
  • Atomic weight: 208.98040(
  • CAS Registry ID: 7440-69-9
  • Group name: Pnictogen
  • Period number: 6
  • Block: p-block
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Description

Bismuth is one of the poor metals that is a bright pink color in its natural solid state. It is the most diamagnetic metal, and in the right conditions it has semi-conductive characteristics. Bismuth has an atomic weight of 208.98040, a melting point of 520.7 °F, and a boiling point of 2847 °F. Some common uses of bismuth include: as an active ingredient in anti-diarrhea medications, as a component in some alloys, as a carrier for fuel in nuclear reactors, and as a component in some glazes.

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Isolation

Bismuth is extracted and isolated from such ores as bismuthinite and bismite. It is also collected as a by-product from other metal ore processing.

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Bismuthinite is a mineral composed of bismuth sulfide and it often occurs with lead and copper ore, and bismite is composed of bismuth oxide. The isolation techniques used to extract pure bismuth from these ores is relatively simple. Most of the bismuth collected for commercial uses is extracted as a by product from copper, gold, lead, silver, and tin processing. Smelting processes used to separate these ores results in bismuth isolation. Smelting is a type of extractive metallurgy that is used to isolate metals from the ores that they are found in. During the smelting process, carbon in the form of coke serves as a reducing agent to reduce the oxidized states of the ore. This process can be used on bismuth by-products from ore processing, or directly on the bismite mineral. The carbon reacts with the oxygen producing carbon monoxide, or carbon dioxide, to leave the metal. Contaminants usually remain, and additional reduction using charcoal or coke further reduce and isolate the bismuth.


General
Name Bismuth
Symbol Bi
Number 83
Chemical series poor metals
Group 15
Period 6
Block p
Appearance lustrous pink
Standard atomic weight 208.98040(1)  g·mol−1
Electron configuration [Xe] 4f14 5d10 6s2 6p3
Electrons per shell 2, 8, 18, 32, 18, 5
Atomic properties
Crystal structure rhombohedral
Oxidation states 3, 5 (mildly acidic oxide)
Electronegativity 2.02 (scale Pauling)
Ionization energies 1st:  703  kJ·mol−1
(more) 2nd:  1610  kJ·mol−1
(more) 3rd:  2466  kJ·mol−1
Atomic radius 160 pm
Atomic radius (calc.) 143 pm
Covalent radius 146 pm
Van der Waals radius
Physical properties
Phase solid
Density (near r.t.) 9.78  g·cm−3
Liquid density at m.p. 10.05  g·cm−3
Melting point 544.7 K (271.5 °C, 520.7 °F)
Boiling point 1837 K (1564 °C, 2847 °F)
Critical point
Heat of fusion 11.30  kJ·mol−1
Heat of vaporization 151  kJ·mol−1
Heat capacity (25 °C) 25.52  J·mol−1·K−1
Miscellaneous
Magnetic ordering diamagnetic
Electrical resistivity (20 °C) 1.29 µ Ω·m
Thermal conductivity (300 K) 7.97  W·m−1·K−1
Thermal expansion (25 °C) 13.4  µm·m−1·K−1
Speed of sound (thin rod) (20 °C) 1790 m/s
Young's modulus 32 GPa
Shear modulus 12 GPa
Bulk modulus 31 GPa
Poisson ratio 0.33
Mohs hardness 2.25
Vickers hardness
Brinell hardness 94.2 MPa
CAS registry number 7440-69-9

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