Calcium

20

Ca

40.078(4)

  • Name: Calcium
  • Symbol: Ca
  • Atomic number: 20
  • Atomic weight: 40.078(4)
  • CAS Registry ID: 7440-70-2
  • Group name: Alkaline earth metal
  • Period number: 4
  • Block: s-block
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Description

Calcium is an alkaline earth metal that is a silvery white solid in its natural state. Calcium readily reacts with water and it forms a layer of oxide and nitride coating if it is exposed to the air. Calcium has an atomic weight of 40.078, a melting point of 1548 °F, and a boiling point of 2703 °F. Some common uses of calcium include: in the formation of quicklime, limestone, and slaked lime, as an ingredient in Portland cement, in calcium chloride for ice removal on roads, as an ingredient in vitamins and food additives, and as an ingredient in fertilizers.

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Isolation

Calcium is not found in its pure form in nature, and there are two main processes that are used to isolate calcium.

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Calcium in the form of sedentary rock can be found in such minerals as calcite, dolomite, and gypsum. The most frequently used calcium isolation method for industrial purposes uses electrolysis. During this process, calcium chloride is produced by reacting hydrochloric acid with calcium carbonate. The results of this reaction include calcium chloride, water, and carbon dioxide. The liquid calcium chloride is then subject to electrolysis; the cathode calcium is separated from the anode chloride.

There are two processes that can be used to isolate a small amount of calcium. The first process uses the reducing reaction between lime, (CaO), and aluminum; the results of this reaction include pure calcium and Ca3Al2O6. The second isolation process uses the reducing reaction between calcium chloride with metal sodium; the end result of this reaction is pure calcium and sodium chloride. These processes are not frequently used as pure calcium that has been isolated for industrial purposes is easily obtained commercially.


General
Name Calcium
Symbol Ca
Number 20
Chemical series alkaline earth metals
Group 2
Period 4
Block s
Appearance silvery white
Standard atomic weight 40.078(4) g·mol−1
Electron configuration [Ar] 4s2
Electrons per shell 2, 8, 8, 2
Atomic properties
Crystal structure cubic face centered
Oxidation states 2 (strongly basic oxide)
Electronegativity 1.00 (Pauling scale)
Ionization energies 1st: 589.8 kJ·mol−1
(more) 2nd: 1145.4 kJ·mol−1
(more) 3rd: 4912.4 kJ·mol−1
Atomic radius 180 pm
Atomic radius (calc.) 194 pm
Covalent radius 174 pm
Van der Waals radius
Physical properties
Phase solid
Density (near r.t.) 1.55 g·cm−3
Liquid density at m.p. 1.378 g·cm−3
Melting point 1115 K (842 °C, 1548 °F)
Boiling point 1757 K (1484 °C, 2703 °F)
Critical point
Heat of fusion 8.54 kJ·mol−1
Heat of vaporization 154.7 kJ·mol
Heat capacity (25 °C) 25.929 J·mol−1·K−1
Miscellaneous
Magnetic ordering paramagnetic
Electrical resistivity (20 °C) 33.6 nΩ·m
Thermal conductivity (300 K) 201 W·m−1·K−1
Thermal expansion (25 °C) 22.3 µm·m−1·K−1
Speed of sound (thin rod) (20 °C) 3810 m/s
Young's modulus 20 GPa
Shear modulus 7.4 GPa
Bulk modulus 17 GPa
Poisson ratio 0.31
Mohs hardness 1.75
Vickers hardness
Brinell hardness 167 MPa
CAS registry number 7440-70-2

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