Iron

26

Fe

55.845(2)

  • Name: Iron
  • Symbol: Fe
  • Atomic number: 26
  • Atomic weight: 55.845(2)
  • CAS Registry ID: 7439-89-6
  • Group name: (none)
  • Period number: 4
  • Block: d-block
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Description

Iron is one of the transition metals that has a gray metallic luster in its natural solid state. Iron is the most abundant element, 35% of the Earth’s mass is composed of iron, and it is one of the most used metals in the world. Iron has an atomic mass of 55.845, a melting point of 2800 °F, and a boiling point of 5182 °F. Iron is most commonly used in different types of metallic alloys for many various purposes.

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Isolation

Iron is never found freely in nature, so various isolation purposes are used to isolate iron from minerals that it is found in.

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Iron ore, such as hematite and magnetite, are where most of the iron that is used for industrial purposes comes from. Hematite is composed of the iron (III) oxide, and magnetite is composed of the iron (II, III) oxide. The iron is isolated from these minerals through a carbon reaction that is carried out in a blast furnace.

The furnace is heated to 3632 °F, coke which serves as the carbon source is added to furnace with the iron ore, and a flux like limestone is fed through the top of the furnace. Heated air is continually pushed into the bottom of the furnace to maintain the high temperatures. In the furnace, the coke and oxygen react to form carbon monoxide. The carbon monoxide reduce the iron ore resulting in pure iron and carbon dioxide. The limestone, or flux, melts other impurities inside the iron to further purify the iron ore.


General
Name Iron
Symbol Fe
Number 26
Chemical series transition metals
Group 8
Period 4
Block d
Appearance lustrous metallic
Standard atomic weight 55.845(2) g·mol−1
Electron configuration [Ar] 4s2 3d6
Electrons per shell 2, 8, 14, 2
Atomic properties
Crystal structure body-centered cubic
Oxidation states 2, 3, 4, 6 (amphoteric oxide)
Electronegativity 1.83 (Pauling scale)
Ionization energies 1st: 762.5 kJ·mol−1
(more) 2nd: 1561.9 kJ·mol−1
(more) 3rd: 2957 kJ·mol−1
Atomic radius 140 pm
Atomic radius (calc.) 156 pm
Covalent radius 125 pm
Van der Waals radius
Physical properties
Phase solid
Density (near r.t.) 7.86 g·cm−3
Liquid density at m.p. 6.98 g·cm−3
Melting point 1811 K (1538 °C, 2800 °F)
Boiling point 3134 K (2861 °C, 5182 °F)
Critical point
Heat of fusion 13.81 kJ·mol−1
Heat of vaporization 340 kJ·mol−1
Heat capacity (25 °C) 25.10 J·mol−1·K−1
Miscellaneous
Magnetic ordering ferromagnetic
Electrical resistivity (20 °C) 96.1 nΩ·m
Thermal conductivity (300 K) 80.4 W·m−1·K−1
Thermal expansion (25 °C) 11.8 µm·m−1·K−1
Speed of sound (thin rod) (r.t.) (electrolytic) 5120 m·s−1
Young's modulus 211 GPa
Shear modulus 82 GPa
Bulk modulus 170 GPa
Poisson ratio 0.29
Mohs hardness 4.0
Vickers hardness 608 MPa
Brinell hardness 490 MPa
CAS registry number 7439-89-6

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